| Title : Enantioselective hydrolysis of (RS)-isopropylideneglycerol acetate with Kluyveromyces marxianus - Molinar_2004_Tetrahedron.Asymmetry_15_1945 |
| Author(s) : Molinari F , Cavenago KS , Romano A , Romano D , Gandolfi R |
| Ref : Tetrahedron Asymmetry , 15 :1945 , 2004 |
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Abstract :
The hydrolysis of (RS)-isopropylideneglycerol acetate with whole cells of the yeast Kluyveromyces marxianus is reported. The biotransformation furnished (R)-isopropylideneglycerol as major enantiomer with good enantioselectivity (E=28) under optimised conditions. The reaction can be performed in an ultrafiltration-membrane reactor allowing for the obtainment of 19.2 g/L of enantiomerically pure (R)-isopropylideneglycerol acetate starting from 60 g/L of racemic mixture. |
| PubMedSearch : Molinar_2004_Tetrahedron.Asymmetry_15_1945 |
| PubMedID: |
| Substrate | IPG-caprylate IPG-butyrate IPG-acetate |
Molinari F, Cavenago KS, Romano A, Romano D, Gandolfi R (2004)
Enantioselective hydrolysis of (RS)-isopropylideneglycerol acetate with Kluyveromyces marxianus
Tetrahedron Asymmetry
15 :1945
Molinari F, Cavenago KS, Romano A, Romano D, Gandolfi R (2004)
Tetrahedron Asymmetry
15 :1945