| Title : A facile synthesis of 4,6-O-benzylidene-D-glycals via 1,5-anhydro-4,6-O-benzylidene-D-hex-1-en-3-ulose - Sakakibara_2008_Carbohydr.Res_343_2740 |
| Author(s) : Sakakibara T , Ito T , Kotaka C , Kajihara Y , Watanabe Y , Fujioka A |
| Ref : Carbohydr Res , 343 :2740 , 2008 |
|
Abstract :
Benzylidenation of readily available 1,5-anhydro-D-hex-1-en-3-ulose, followed by sodium borohydride reduction, afforded the title compounds in high yields. Separation of 4,6-O-benzylidene-D-allal and -D-glucal was accomplished by selective acetylation with lipase PS. |
| PubMedSearch : Sakakibara_2008_Carbohydr.Res_343_2740 |
| PubMedID: 18558400 |
Sakakibara T, Ito T, Kotaka C, Kajihara Y, Watanabe Y, Fujioka A (2008)
A facile synthesis of 4,6-O-benzylidene-D-glycals via 1,5-anhydro-4,6-O-benzylidene-D-hex-1-en-3-ulose
Carbohydr Res
343 :2740
Sakakibara T, Ito T, Kotaka C, Kajihara Y, Watanabe Y, Fujioka A (2008)
Carbohydr Res
343 :2740