| Title : Enzymatic Ring-Opening Polymerization of Lactones Catalyzed by Lipase - Uyama_1993_Chem.Lett_7_1149 |
| Author(s) : Uyama H , Kobayashi S |
| Ref : Chem Lett , 7 :1149 , 1993 |
|
Abstract :
Enzymatic ring-opening polymerization of lactones was achieved by using lipase as catalyst. The polymerization of epsilon-caprolactone by Pseudomonas fluorescens lipase at 60 C in bulk for 10 days afforded a polyester with average molecular weight of 7.0 x 103. From 1H and 13C NMR analysis, the polymer possesses the terminal structure of a carboxylic acid group at one end and a hydroxyl group at the other. |
| PubMedSearch : Uyama_1993_Chem.Lett_7_1149 |
| PubMedID: |
| Substrate | epsilon-caprolactone |
Uyama H, Kobayashi S (1993)
Enzymatic Ring-Opening Polymerization of Lactones Catalyzed by Lipase
Chem Lett
7 :1149
Uyama H, Kobayashi S (1993)
Chem Lett
7 :1149