6-Tuliposide-B

tulip lactone-forming carboxylesterases, specifically catalyzing intramolecular transesterification, and convert 6-tuliposide B to D-glucose and tulipalin B

General

Type : Natural, Carbohydrate

Chemical_Nomenclature : [(2R,3S,4S,5R)-3,4,5,6-tetrahydroxyoxan-2-yl]methyl (3S)-3,4-dihydroxy-2-methylidenebutanoate

Canonical SMILES : C=C(C(CO)O)C(=O)OCC1C(C(C(C(O1)O)O)O)O

InChI : InChI=1S\/C11H18O9\/c1-4(5(13)2-12)10(17)19-3-6-7(14)8(15)9(16)11(18)20-6\/h5-9,11-16,18H,1-3H2\/t5-,6-,7-,8+,9-,11?\/m1\/s1

InChIKey : FMHJNIRDGYFPEC-CHICSPHLSA-N

Other name(s) : 6-tuliposide B  ||  6-O-[(3S)-3,4-Dihydroxy-2-methylenebutanoyl]-D-glucose  ||  CHEBI:87124  ||  C21186


MW : 294.25

Formula : C11H18O9

CAS_number :

PubChem : 25034024

UniChem : FMHJNIRDGYFPEC-CHICSPHLSA-N

Target

Structures : No structure

Families : Plant_carboxylesterase

References (2)

Title : Molecular identification of tuliposide B-converting enzyme: a lactone-forming carboxylesterase from the pollen of tulip - Nomura_2015_Plant.J_83_252
Author(s) : Nomura T , Murase T , Ogita S , Kato Y
Ref : Plant J , 83 :252 , 2015
Abstract :
PubMedSearch : Nomura_2015_Plant.J_83_252
PubMedID: 25997073
Gene_locus related to this paper: tulge-a0a0h5bmx5

Title : The antibacterial properties of 6-tuliposide B. Synthesis of 6-tuliposide B analogues and structure-activity relationship - Shigetomi_2010_Phytochemistry_71_312
Author(s) : Shigetomi K , Shoji K , Mitsuhashi S , Ubukata M
Ref : Phytochemistry , 71 :312 , 2010
Abstract :
PubMedSearch : Shigetomi_2010_Phytochemistry_71_312
PubMedID: 19939419