natural core substrate with lignin-xylan cross-linkage || Natural core substrate with lignin-xylan cross-linkage. Bn-MeGlcA3Xyl3 bears a natural core structure of LCCs (Lignin-carbohydrate complexe) that possesses multiple cleavage sites potentially degradable by carbohydrate esterase (CE) family 15 (GEs)(alpha/beta hydrolase) and not alpha/beta hydrolases on the glucurono-xylan moiety (glycosyl hydrolase (GH) family 30: xylanases [8], GH family 1 and 3: -xylosidases, and GH family 67 and 115: -glucuronidases)
Type : Glycoside, Natural, Glucuronoyl, Carbohydrate
Chemical_Nomenclature :
Canonical SMILES : C1([C@@H](CO[C@H](C1O[C@H]2OC([C@H](C([C@@H]2O)O)OC)C(OCC3=CC=CC=C3)=O)O[C@@H]4CO[C@H]([C@H](C4O)O)O[C@H]5C(C([C@@H](OC5)O)O)O)O)O
InChI : InChI=1S\/C29H42O19\/c1-40-22-18(34)21(37)28(48-24(22)26(39)41-7-11-5-3-2-4-6-11)47-23-15(31)12(30)8-43-29(23)46-14-10-44-27(20(36)17(14)33)45-13-9-42-25(38)19(35)16(13)32\/h2-6,12-25,27-38H,7-10H2,1H3\/t12-,13-,14-,15?,16?,17?,18?,19?,20+,21+,22+,23?,24?,25-,27+,28+,29+\/m1\/s1
InChIKey : FQAIFIGHHQLJNT-LWYQBMFPSA-N
Other name(s) :
Structures : No structure
Families : Glucuronoyl_esterase
Title : Synthesis of a natural core substrate with lignin-xylan cross-linkage for unveiling the productive kinetic parameters of glucuronoyl esterase - Koh_2024_Biochem.Biophys.Res.Commun_734_150642 |
Author(s) : Koh S , Saito Y , Kudo H , Taguchi S , Kumagai A , Mizuno M , Samejima M , Amano Y |
Ref : Biochemical & Biophysical Research Communications , 734 :150642 , 2024 |
Abstract : |
PubMedSearch : Koh_2024_Biochem.Biophys.Res.Commun_734_150642 |
PubMedID: 39316949 |
Gene_locus related to this paper: 9pezi-a0a7g1puy1 |