Nonane-4,6-dione
Hydrolisis of C-C bonds in the beta-diketone is performed by different other enzymes with different mechanisms. Dke1 (diketone-cleaving enzyme from Acinetobacter johnsonii) is a dioxygenase. Fumarylacetoacetate hydrolase with a catalytic His/Asp dyad, aided by a calcium ion. 6-oxocamphor hydrolase cleaves nonenolizable cyclic beta-diketones is a homologue of the crotonase superfamily Grogan et al.
General
Type :
Chemical_Nomenclature : nonane-4,6-dione
Canonical SMILES : CCCC(=O)CC(=O)CCC
InChI : InChI=1S\/C9H16O2\/c1-3-5-8(10)7-9(11)6-4-2\/h3-7H2,1-2H3
InChIKey : ZDYWPVCQPUPOJV-UHFFFAOYSA-N
Other name(s) : 4,6-nonanedione || 4,6-dioxononane || 75JZE9JA5F || CHEBI:16111
MW :
Formula : C9H16O2
CAS_number : 14090-88-1
PubChem : 26454
UniChem : ZDYWPVCQPUPOJV-UHFFFAOYSA-N
Target
Structures : No structure
Families : AlphaBeta_hydrolase
References (3)
| Title : Emergent mechanistic diversity of enzyme-catalysed beta-diketone cleavage - Grogan_2005_Biochem.J_388_721 |
| Author(s) : Grogan G |
| Ref : Biochemical Journal , 388 :721 , 2005 |
| Abstract : |
| PubMedSearch : Grogan_2005_Biochem.J_388_721 |
| PubMedID: 15934927 |
| Gene_locus related to this paper: psesp-OPH |
| Title : Biochemical and molecular characterization of a periplasmic hydrolase for oxidized polyvinyl alcohol from Sphingomonas sp. strain 113P3 - Klomklang_2005_Microbiology_151_1255 |
| Author(s) : Klomklang W , Tani A , Kimbara K , Mamoto R , Ueda T , Shimao M , Kawai F |
| Ref : Microbiology , 151 :1255 , 2005 |
| Abstract : |
| PubMedSearch : Klomklang_2005_Microbiology_151_1255 |
| PubMedID: 15817792 |
| Gene_locus related to this paper: sphs1-OPH |
| Title : The gene pvaB encodes oxidized polyvinyl alcohol hydrolase of Pseudomonas sp. strain VM15C and forms an operon with the polyvinyl alcohol dehydrogenase gene pvaA - Shimao_2000_Microbiology_146 ( Pt 3)_649 |
| Author(s) : Shimao M , Tamogami T , Kishida S , Harayama S |
| Ref : Microbiology , 146 ( Pt 3) :649 , 2000 |
| Abstract : |
| PubMedSearch : Shimao_2000_Microbiology_146 ( Pt 3)_649 |
| PubMedID: 10746768 |
| Gene_locus related to this paper: psesp-OPH |