Diclofop-methyl
Carboxyesterases activate aryloxyphenoxypropionate (AOPP) graminicides to their bioactive herbicidal acids by hydrolysing the respective ester precursors. Some are alpha/beta hydrolases other are SGNH hydrolases (Cummins et al. Hongming et al.)
General
Type : Herbicide, Propionate
Chemical_Nomenclature : methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate
Canonical SMILES : CC(C(=O)OC)OC1=CC=C(C=C1)OC2=C(C=C(C=C2)Cl)Cl
InChI : InChI=1S\/C16H14Cl2O4\/c1-10(16(19)20-2)21-12-4-6-13(7-5-12)22-15-8-3-11(17)9-14(15)18\/h3-10H,1-2H3
InChIKey : BACHBFVBHLGWSL-UHFFFAOYSA-N
Other name(s) : Diclofop methyl || Illoxan || Dichlorfop-methyl || Hoelon || SCHEMBL55275 || CHEMBL34474 || CHEBI:4510 || CHEBI:145412
MW : 341.2
Formula : C16H14Cl2O4
CAS_number : 51338-27-3
PubChem : 39985
UniChem : BACHBFVBHLGWSL-UHFFFAOYSA-N
Target
Structures : No structure
Families : 6_AlphaBeta_hydrolase, Carb_B_Chordata
References (7)
| Title : Enantioselective in vitro metabolism of the herbicide diclofop-methyl: Prediction of toxicokinetic parameters and reaction phenotyping - Barbetta_2023_J.Pharm.Biomed.Anal_235_115639 |
| Author(s) : Barbetta MFS , Perovani IS , Duarte LO , de Oliveira ARM |
| Ref : J Pharm Biomed Anal , 235 :115639 , 2023 |
| Abstract : |
| PubMedSearch : Barbetta_2023_J.Pharm.Biomed.Anal_235_115639 |
| PubMedID: 37619294 |
| Title : A novel esterase LanE from Edaphocola flava HME-24 and the enantioselective degradation mechanism of herbicide lactofen - Hu_2020_Ecotoxicol.Environ.Saf_205_111141 |
| Author(s) : Hu T , Xiang Y , Chen Q , Shang N , Xu M , Huang X |
| Ref : Ecotoxicology & Environmental Safety , 205 :111141 , 2020 |
| Abstract : |
| PubMedSearch : Hu_2020_Ecotoxicol.Environ.Saf_205_111141 |
| PubMedID: 32846294 |
| Gene_locus related to this paper: 9bact-a0a7g9u6e3 |
| Title : Identification and characterization of a novel carboxylesterase (FpbH) that hydrolyzes aryloxyphenoxypropionate herbicides - Wang_2017_Biotechnol.Lett_39_553 |
| Author(s) : Wang C , Qiu J , Yang Y , Zheng J , He J , Li S |
| Ref : Biotechnol Lett , 39 :553 , 2017 |
| Abstract : |
| PubMedSearch : Wang_2017_Biotechnol.Lett_39_553 |
| PubMedID: 28058522 |
| Gene_locus related to this paper: burvg-a4jl51 |
| Title : Isolation of an aryloxyphenoxy propanoate (AOPP) herbicide-degrading strain Rhodococcus ruber JPL-2 and the cloning of a novel carboxylesterase gene (feh) - Hongming_2015_Braz.J.Microbiol_46_425 |
| Author(s) : Hongming L , Xu L , Zhaojian G , Fan Y , Dingbin C , Jianchun Z , Jianhong X , Shunpeng L , Qing H |
| Ref : Braz J Microbiol , 46 :425 , 2015 |
| Abstract : |
| PubMedSearch : Hongming_2015_Braz.J.Microbiol_46_425 |
| PubMedID: 26273257 |
| Title : Exposure to difenoconazole, diclofop-methyl alone and combination alters oxidative stress and biochemical parameters in albino rats - Abd-Alrahman_2014_Int.J.Clin.Exp.Med_7_3637 |
| Author(s) : Abd-Alrahman SH , Elhalwagy ME , Kotb GA , Farid H , Farag AA , Draz HM , Isa AM , Sabico S |
| Ref : Int J Clin Exp Med , 7 :3637 , 2014 |
| Abstract : |
| PubMedSearch : Abd-Alrahman_2014_Int.J.Clin.Exp.Med_7_3637 |
| PubMedID: 25419412 |
| Title : Degradation of cyhalofop-butyl (CyB) by Pseudomonas azotoformans strain QDZ-1 and cloning of a novel gene encoding CyB-hydrolyzing esterase - Nie_2011_J.Agric.Food.Chem_59_6040 |
| Author(s) : Nie ZJ , Hang BJ , Cai S , Xie XT , He J , Li SP |
| Ref : Journal of Agricultural and Food Chemistry , 59 :6040 , 2011 |
| Abstract : |
| PubMedSearch : Nie_2011_J.Agric.Food.Chem_59_6040 |
| PubMedID: 21534595 |
| Gene_locus related to this paper: pseaz-e9nwd3 |
| Title : Purification and cloning of an esterase from the weed black-grass (Alopecurus myosuroides), which bioactivates aryloxyphenoxypropionate herbicides - Cummins_2004_Plant.J_39_894 |
| Author(s) : Cummins I , Edwards R |
| Ref : Plant J , 39 :894 , 2004 |
| Abstract : |
| PubMedSearch : Cummins_2004_Plant.J_39_894 |
| PubMedID: 15341632 |