3-Hydroxydecanoyl-3-hydroxydecanoic-acid
Product of the reaction of RhlA. The most abundant HAA found in extracellular rhamnolipids, beta-hydroxydecanoyl-beta-hydroxydecanoate. The stereochemistry of the chiral center of the -hydroxyacids is the same as that found in the beta-hydroxy intermediates in fatty acid biosynthesis. RhlA forms one molecule of beta-hydroxydecanoyl-beta-hydroxydecanoate from two molecules of -betahydroxydecanoyl-ACP
General
Type : Natural, Fatty acid
Chemical_Nomenclature : 3-(3-hydroxydecanoyloxy)decanoic acid
Canonical SMILES : CCCCCCCC(CC(=O)OC(CCCCCCC)CC(=O)O)O
InChI : InChI=1S\/C20H38O5\/c1-3-5-7-9-11-13-17(21)15-20(24)25-18(16-19(22)23)14-12-10-8-6-4-2\/h17-18,21H,3-16H2,1-2H3,(H,22,23)
InChIKey : ZFPAFAWFRTWCSK-UHFFFAOYSA-N
Other name(s) : beta-hydroxydecanoyl-beta-hydroxydecanoate || (R,R)-3-(3-hydroxydecanoyloxy)decanoate || 3-hydroxydecanoyl-3-hydroxydecanoic acid || 3-[(3-hydroxydecanoyl)oxy]decanoic acid || Compound NP-021469 || SCHEMBL19439386 || CHEBI:62406
Target
Structures : No structure
Families : HAA-synthase-thioesterase-RhlA-PhaG
References (1)
| Title : RhlA converts beta-hydroxyacyl-acyl carrier protein intermediates in fatty acid synthesis to the beta-hydroxydecanoyl-beta-hydroxydecanoate component of rhamnolipids in Pseudomonas aeruginosa - Zhu_2008_J.Bacteriol_190_3147 |
| Author(s) : Zhu K , Rock CO |
| Ref : Journal of Bacteriology , 190 :3147 , 2008 |
| Abstract : |
| PubMedSearch : Zhu_2008_J.Bacteriol_190_3147 |
| PubMedID: 18326581 |
| Gene_locus related to this paper: pseae-rhla |