4,4'-MDA
Hydrolysis of PBA-PU by polyurethanase and esterase give 4,4'-MDA Diaminodiphenylmethane, adipic acid and butanediol
General
Type :
Chemical_Nomenclature : 4-[(4-aminophenyl)methyl]aniline
Canonical SMILES : C1=CC(=CC=C1CC2=CC=C(C=C2)N)N
InChI : InChI=1S\/C13H14N2\/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11\/h1-8H,9,14-15H2
InChIKey : YBRVSVVVWCFQMG-UHFFFAOYSA-N
Other name(s) : 4,4'-Methylenedianiline || 4,4'-Diaminodiphenylmethane || Dadpm || RefChem:506839 || CHEMBL85728 || SCHEMBL2196895 || SCHEMBL5253436 || SCHEMBL6424853
MW : 198.26
Formula : C13H14N2
CAS_number : 101-77-9
PubChem : 7577
UniChem : YBRVSVVVWCFQMG-UHFFFAOYSA-N
Target
Structures : No structure
Families : Cutinase
References (3)
| Title : Polyurethane Cascade Depolymerization by a Combination of Thermal Pretreatment and Enzymatic Hydrolysis - Sun_2026_ChemSusChem_19_e202502633 |
| Author(s) : Sun S , Subramaniyan S , Ranjani G , Cid Gomes L , Bernin D , Bayer T , Bornscheuer UT , Hakkarainen M , Syren PO |
| Ref : ChemSusChem , 19 :e202502633 , 2026 |
| Abstract : |
| PubMedSearch : Sun_2026_ChemSusChem_19_e202502633 |
| PubMedID: 41773588 |
| Gene_locus related to this paper: humin-cut |
| Title : Screening putative polyester polyurethane degrading enzymes with semi-automated cell-free expression and nitrophenyl probes - Ahsan_2024_Synth.Biol.(Oxf)_9_ysae005 |
| Author(s) : Ahsan A , Wagner D , Varaljay VA , Roman V , Kelley-Loughnane N , Reuel NF |
| Ref : Synth Biol (Oxf) , 9 :ysae005 , 2024 |
| Abstract : |
| PubMedSearch : Ahsan_2024_Synth.Biol.(Oxf)_9_ysae005 |
| PubMedID: 38414826 |
| Gene_locus related to this paper: papla-Plcut1 , 9pezi-a0ab34kzm2 |
| Title : Biodegradation of polyester polyurethane by Cladosporium sp. P7: Evaluating its degradation capacity and metabolic pathways - Liu_2023_J.Hazard.Mater_448_130776 |
| Author(s) : Liu J , Zeng Q , Lei H , Xin K , Xu A , Wei R , Li D , Zhou J , Dong W , Jiang M |
| Ref : J Hazard Mater , 448 :130776 , 2023 |
| Abstract : |
| PubMedSearch : Liu_2023_J.Hazard.Mater_448_130776 |
| PubMedID: 36706489 |