Fenvalerate-analog-fluo-CpdII
fluorogenic analog of cypermethrin. Compound I (acid derivative) is a general esterase substrate; Compound II is a pyrethroid-selective substrate Two chiral centers. The most insecticidal isomer is alphaS 2S
General
Type : Insecticide, Naphthalen, Not AlphaBeta Hydrolase target, Cyanide
Chemical_Nomenclature : [(S)-cyano-(6-methoxynaphthalen-2-yl)methyl] (2S)-2-(4-chlorophenyl)-3-methylbutanoate
Canonical SMILES : CC(C)C(C1=CC=C(C=C1)Cl)C(=O)OC(C#N)C2=CC3=C(C=C2)C=C(C=C3)OC
InChI : InChI=1S\/C24H22ClNO3\/c1-15(2)23(16-6-9-20(25)10-7-16)24(27)29-22(14-26)19-5-4-18-13-21(28-3)11-8-17(18)12-19\/h4-13,15,22-23H,1-3H3\/t22-,23+\/m1\/s1
InChIKey : RNOMFEBDDQRARB-PKTZIBPZSA-N
Other name(s) : Compound II
MW : 407.9
Formula : C24H22ClNO3
CAS_number :
PubChem : 101246213, 101246216, 101246217, 101246212
UniChem : RNOMFEBDDQRARB-PKTZIBPZSA-N
Target
Structures : No structure
Families : Carb_B_Arthropoda
References (2)
| Title : Hydrolysis of individual isomers of fluorogenic pyrethroid analogs by mutant carboxylesterases from Lucilia cuprina - Devonshire_2007_Insect.Biochem.Mol.Biol_37_891 |
| Author(s) : Devonshire AL , Heidari R , Huang HZ , Hammock BD , Russell RJ , Oakeshott JG |
| Ref : Insect Biochemistry & Molecular Biology , 37 :891 , 2007 |
| Abstract : |
| PubMedSearch : Devonshire_2007_Insect.Biochem.Mol.Biol_37_891 |
| PubMedID: 17681228 |
| Gene_locus related to this paper: luccu-E3aest7 |
| Title : Development of sensitive esterase assays based on alpha-cyano-containing esters - Shan_2001_Anal.Biochem_299_54 |
| Author(s) : Shan G , Hammock BD |
| Ref : Analytical Biochemistry , 299 :54 , 2001 |
| Abstract : |
| PubMedSearch : Shan_2001_Anal.Biochem_299_54 |
| PubMedID: 11726184 |